Hydrazinsulfat mit dem "Ugine Kuhkmann (Atochem) Process

[bombjack]

Meine Versuchsreihe auf VC:

http://www.versuchschemie.de/ptopic,243359.html

Ersatz von ACN mit Carbonsäureestern und diverse andere Möglichkeiten z.B. Verwendung von Peressigsäure als Wasserstoffperoxidersatz vgl.
http://www.versuchschemie.de/ptopic,243845,.html#243845


bombjack

[Mephisto]

Nur Links, kein Copy&Paste

Schön dokumentiert ist es allemal. Diesen Roth Autoklaven will ich selbst nie mehr missen müssen. Sehr praktisches Ding!

[Butandiolmonoacrylat]

Wow, eine sehr einfache Darstellungsmethode ganz ohne Gelatine Danke für die Versuche und die detaillierte Dokumentation.

MfG

[bombjack]

Das mit der Peressigsäure vgl.  http://www.freepatentsonline.com/3959262.pdf würde (werde, wenn Zeit) ich gerne mal ausprobieren:

[...]
EXAMPLE 7

A solution of peracetic acid was prepared by mixing 17.3 gm of glacial acetic acid (0.29 moles), 7.2 gm of a 68% by weight aqueous solution of hydrogen peroxide and 0.7 gm of concentrated sulfuric acid and reacting this mixture for several hours at ambient temperature. In this manner, a solution containing 0.10 moles of peracetic acid and 0.033 moles of unreacted hydrogen peroxide was obtained. This solution was added over a period of 30 minutes at 20°C to a solution of 8.5 gm ammonia (0.5 moles), 14.5 gm acetone (0.25 moles), 25 gm water and 0.25 gm of the disodium salt of ethylendiaminetetraacetic acid in 40 gm of methanol while at the same time passing a stream of gaseous ammonia, about 0.1 moles/hour, through the mixture. The mixture was left to react for fifteen minutes at this temperature and then titrated. 8.5 gm of acetoneazine (0.076 moles) corresponding to a yield of 76% by comparison to the total amount of peracid were found.

EXAMPLE 8

A 57% by weight aqueous solution of peracetic acid (0.10 moles) was added to a solution of 8.5 gm ammonia (0.5 moles) 14.5 gm of acetone (0.25 moles) and 0.25 gm of the disodium salt of ethylenediaminetetraacetic acid in 60 gm of water over a period of 30 minutes at 20°C. 8.1 gm of acetoneazine (0.072 moles) formed corresponding to a yield of 72% by comparison with the total amount of peracid.

EXAMPLE 9

A 24% by weight solution of peracetic acid (0.10 moles) in acetone (0.40 moles) was added to 57 gm of an aqueous solution of ammonia containing 15% ammonia by weight (0.5 moles) over 30 minutes at 20°C and left to react at this temperature for 30 minutes. 8.3 gm of acetoneazine (0.074 moles) formed corresponding to a yield of 74% by comparison with the total amount of peracid.
[...]

besonders da es diese als Desinfektionsmittel mit bis zu 40% Peressigsäure gibt.....und da sollte das Example 9 wunderbar funktionieren....

bombjack